Preheat Oven
Preheat your oven to 350°F (175°C). Line an 8x8-inch baking pan with parchment paper and grease lightly.
Make the Brownie Batter
In a bowl, whisk together melted butter, granulated sugar, and brown sugar. Add eggs and vanilla, whisking until glossy.
Sift in flour, cocoa powder, salt, and espresso powder. Stir until just combined, then fold in chocolate chips.
Bake the Brownies
Pour batter into the prepared pan. Bake for 20–25 minutes, until edges are set but the center is slightly soft. Let cool completely.
Make the Chocolate Mousse
Heat ¾ cup heavy cream in a saucepan until just simmering. Pour over chocolate chips in a bowl, let sit for 2 minutes, then whisk smooth. Let cool to room temperature.
In another bowl, whip the remaining cream with powdered sugar and vanilla until soft peaks form. Fold into cooled chocolate mixture until airy.
Assemble
Spread mousse evenly over cooled brownies. Smooth the top with a spatula. Chill for 2–3 hours until set.
Serve
Dust with cocoa powder, top with shaved chocolate, or add whipped cream before slicing into squares.